Why is it the opposite in both experiment? (i.e. maxima occurs for multiple of λ/2 in single slit diffraction but for YDSE multiples of λ/2 are where dark fringes occur).
When two point sources separated by some distance $d$ produce waves in phase, they will produce constructive interference at any point $P$ for which the path difference from the sources is $n \lambda$. I believe this is more or less clear, do you see it? Since two very narrow slits may be considered, for this purpose, as point sources, this results also applies for Young's (very narrow)double-slit experiment.
When you have 1 slit with finite width, the usual approach is to consider the slit to be divided into several tiny strips (point sources) each of which produce waves. The following image is taken from Young and Freedman's book, in which the topic is nicely explained), considering 2 little strips in the slit, but the same reasoning applies considering 4, 6, 8,... strips
yielding that you get dark bands at $y_m = x \frac{m \lambda}{a}$. In the book you may find a more detailed explanation.
Why is the central maximum in diffraction is twice as wide as the other secondary maxima?
You may look at this using the formula. Basically it is because the central maxima goes from $m = -1$ to $m = 1$ (it jumps two values of $m$) while the secondary maxima jumps only 1 value in $m$ (e.g. from $m=1$ to $m=2$.)
Why is diffraction measured in radian while fringe width in mm?
I don't know what you mean by this. You may measure in radians the angular position of some maxima/minima from the normal line coming from the slits. You can do something similar to measure the width of the lobes in the diffraction pattern. Equivalently, you may measure the locations or the widths of the lobes in mm as distances over the screen.