If maximum static friction force would be expressed in vector form it would be:
$$ \large{\vec{F}_{max} = -\mu_{s}\cdot\|\vec{F}_n\| \cdot \hat{\textbf{u}}_{\perp F_n}} $$
here,
- $\mu_{s}$ - static friction coefficient
- $\vec{F}_n$ - normal force
- $\hat{\textbf{u}}_{\perp F_n}$ - unit vector of applied external force perpendicular to normal force vector
So, there is no static friction force if :
- surfaces are friction-less
- no normal force is exerted on body (for example, weightlessness mode in free-falling bodies)
- no external force applied perpendicular to normal force
As a side-note,- if static friction force would exist without external force applied,- then body which have been put on flat surface, would have started to move itself with acceleration (second Newton law), without any apparent reason. Thus it would break causality.
However, surface features which causes friction force,- called asperities-, exists always no matter friction force is induced or not. Asperities:
As a bonus points. Typical earthquake is caused by the same friction mechanism when static friction force is not able to hold-on pair of drifting tectonic plates glued together anymore.