When the car brakes, the normal reaction force on the front wheels will be greater than the normal reaction force on the rear wheel. This is necessary to oppose the counter-clockwise moment created about the center of mass (COM) by the static friction braking forces acting backward on the wheels (without locking the brakes). See the Figures below (which neglects the effects of air resistance).
For simplicity, it is assumed the contact points with the road between the front and rear wheels are symmetric about the COM. FIG 1 shows the vehicle without braking or accelerating. Given the symmetry about the COM the normal force acting on each wheel is one force the weight of the vehicle so that the sum of the moments about the COM are zero.
FIG 2 shows the vehicle braking. The situation on the other two wheels (not shown) is identical by symmetry. Each wheel is subject to a rearward static friction force applied by the road. For equilibrium we have
$$\sum M_{COM}=N_{R}L+2fh-N_{F}L=0\tag{1}$$
$$N_{F}=N_{R}+\frac{2fh}{L}\tag{2}$$
$$\sum F_{V}=-\frac{Mg}{2}+N_{F}+N_{R}=0\tag{3}$$
$$N_{F}+N_{R}=\frac{Mg}{2}\tag{4}$$
Combining equations (2) and (4)
$$N_{F}=\frac{Mg}{4}+\frac{fh}{L}\tag{5}$$
$$N_{R}=\frac{Mg}{4}-\frac{fh}{L}\tag{6}$$
We see that braking reduces the normal force on the rear wheels (and thus the pressure on the rear wheels) and increases the normal force on the front wheels (and thus the pressure on the front wheels) from what they were before braking (or accelerating). For this example due to symmetry the static friction force $f$ on each wheel is one forth the total static friction force $f_{tot}$ acting on all wheels, or
$$f=\frac{f_{tot}}{4}=M\frac{a}{4}$$
Where $a$ is the deceleration of the car during braking (assumed constant).
Hope this helps