Rutherford model for scattering explicitly assumes that the $\alpha$ particle does not actually penetrate the nuclear region, so that the particle and the nucleus (both assumed to be spherical) act like point charges as far as the Coulomb force is concerned.
To answer your question, yes of course there is a non-zero probability of the particle tunneling through the nucleus for $\theta=0^\circ$. But we are not concerned with that quantum mechanical effect while calculating scattering angles and other parameters.
For the second part, technically not true since you may have already guessed by putting $\theta=180^\circ$ in the formula. I think you should look how the differential cross section is defined-
The number $dN$ of $\alpha$ particles scattered into a solid angle $d\Omega$ at scattering angle $\theta$ is given by
$$dN=\frac{\mathrm d\sigma}{\mathrm d\Omega}~Ind\Omega$$ (I is the number of $\alpha$ particles incident, $n$ is the number of nuclei per $cm^2$ of the target foil)
This is the differential cross section; finite for all allowed values of $\theta$
Whereas the total cross section IS infinite given by
$$\sigma_T = \int_0^{2 \pi} d \phi \int_0^\pi \frac{d \sigma}{d \Omega} \sin \theta d \theta$$
That the total cross section is infinite just means that every charged particle that passes by the (bare) nucleus is scattered to some extent.