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Quantum mechanics describes the microscopic properties of nature in a regime where classical mechanics no longer applies. It explains phenomena such as the wave-particle duality, quantization of energy, and the uncertainty principle and is generally used in single-body systems. Use the quantum-field-theory tag for the theory of many-body quantum-mechanical systems.

115 votes
6 answers
31k views

What is the physical meaning of commutators in quantum mechanics?

At that stage one is fairly comfortable with the concept of wavefunctions and with the Schrödinger equation, and has had some limited exposure to operators. … One common case, for example, is to explain that some operators commute and that this means the corresponding observables are 'compatible' and that there exists a mutual eigenbasis; the commutation relation …
Emilio Pisanty's user avatar
34 votes
11 answers
10k views

Half-integer eigenvalues of orbital angular momentum

Why do we exclude half-integer values of the orbital angular momentum? It's clear for me that an angular momentum operator can only have integer values or half-integer values. … Of course, when we do the experiments we confirm that a scalar wavefunction and integer spherical harmonics are enough to describe everything. …
Stephen Dedalus's user avatar
28 votes
2 answers
6k views

Why does the classical Noether charge become the quantum symmetry generator?

It is easy to prove that this is equivalent to $[U,H] = 0$ for all $U$ representing the transformation, where $H$ is the Hamiltonian operator. … Presumably after quantization these can be associated to the Lie algebra generators, acting on wavefunctions on the manifold. Does this sound right to anyone? …
Edward Hughes's user avatar
27 votes
3 answers
3k views

Is there a "position operator" for the "particle on a ring" quantum mechanics model?

For this quantum mechanical system, is there an operator that corresponds to "position" the same way that there are operators corresponding to angular momentum and energy? … My first guess for what the operator would be is $$ \hat \Phi \big[ \psi(\phi) \big] = \phi \, \psi(\phi) $$ which would be analogous to the position operator for the "particle in a box" system, but I …
Adrian's user avatar
  • 393
27 votes
2 answers
2k views

Is there any theorem that suggests that QM+SR has to be an operator theory?

In wave-function theories we have differential operators (e.g., $-i\nabla$), but these aren't dynamical, so there is a clear distinction between an operator and a differential operator. … \ \text{operator theory} & (\mathrm{QM.1}) & (\mathrm{QFT.1}) \\ \text{wave-function theory} & (\mathrm{QM.2}) & \quad ?? …
AccidentalFourierTransform's user avatar
26 votes
5 answers
14k views

What is the difference between a functional and an operator?

When we define an operator in physics, e.g. the momentum operator as $\hat{p} = i \frac{d}{dx}$, it is said this operator acts on the wave functions. … Why do we call $\hat{p}$ momentum operator and not momentum functional? …
asmaier's user avatar
  • 10k
26 votes
7 answers
6k views

Is the Momentum Operator a Postulate?

One thing that I haven't been able to derive from them, however, is the identity of the momentum operator. … I know that it makes sense, as it results in the Ehrenfest Theorem, the De Broglie wavelength hypothesis, the Heisenberg Uncertainty Principle (for $x$ and $p$), the momentum operator being the generator …
Juan Perez's user avatar
  • 3,012
25 votes
3 answers
3k views

The Origins of the Second Quantization

We all we told that to some extent it makes sense to treat the particle as a Gaussian wave packet. … After the measurement, the wave function collapses and forgets about both 'separate' Gaussians. …
mavzolej's user avatar
  • 3,013
24 votes
7 answers
16k views

How does the momentum operator act on state kets?

($|\alpha\rangle$ is a Gaussian wave packet.) … I think my question boils down to: Does the operator $\hat{p}$ act on the basis kets $|x\rangle$ or on their coefficients? …
Ruvi Lecamwasam's user avatar
22 votes
4 answers
7k views

Applying an operator to a wavefunction vs. a (ket) vector

.$$ However, in class I've also seen operators applied to scalar-valued functions, such as the momentum operator in position space: $$P = - i \hbar \frac{\partial}{\partial x},\quad P \psi(x) = - i \hbar … On the Wikipedia article "Operator (physics)", under "Linear operators in wave mechanics", I found the following: $$A \psi(x) = A \langle x | \psi \rangle = \langle x | A | \psi \rangle$$ However, that …
Socob's user avatar
  • 488
22 votes
1 answer
2k views

What is known about the hydrogen atom in $d$ spatial dimensions?

Can these functions be described as eigenfunctions of $d$-dimensional angular momentum operators, analogous to $L^2$ and $L_z$? If so, what are the eigenvalues? … Is there a reasonable closed form for the $d$-dimensional hydrogenic stationary-state wavefunctions? If not, is there a reasonable (asymptotic) approximation formula? …
David Zhang's user avatar
20 votes
5 answers
11k views

Can the momentum operator have an imaginary expectation value?

I'm making examples of wave functions to incorporate in a QM exam. … I came up with the following wave function, which gives me some troubles: $$\psi(x,0) = \begin{cases} A(a-x), & -a \leq x \leq a,\\ 0& \text{otherwise}. …
Nicolas's user avatar
  • 331
20 votes
4 answers
3k views

Differences between principles of QM and QFT

Wavefunction fundamentalism. All knowable information about a system is encoded in its wavefunction (ignoring phase and normalization). Unitary evolution of the wavefunction. … The wavefunction evolves over time in a deterministic and unitary manner. Observables. Any observable is represented by a Hermitian operator. Inner product. …
user avatar
19 votes
3 answers
1k views

Paradox of wavefunction collapse into an unphysical state

For example, we know that the eigenfunctions of the momentum operator (in 1D for simplicity) $$\hat p = -i \hbar \frac{\partial}{\partial x}$$ are plane waves: $$\psi_p(x) = A e^{ipx/\hbar}$$ These eigenfunctions … If we try to apply the cited postulate to the momentum operator, we would therefore incur in a contradiction: the system cannot jump into an eigenstate of the momentum operator, because such an eigenstate …
valerio's user avatar
  • 16.5k
18 votes
2 answers
2k views

Is the Uncertainty Principle valid for information about the past?

My layman understanding of the Uncertainty Principle is that you can't determine the both the position and momentum of a particle at the same point in time, because measuring one variable changes the other …
John's user avatar
  • 393

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