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Quantum mechanics describes the microscopic properties of nature in a regime where classical mechanics no longer applies. It explains phenomena such as the wave-particle duality, quantization of energy, and the uncertainty principle and is generally used in single-body systems. Use the quantum-field-theory tag for the theory of many-body quantum-mechanical systems.
115
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What is the physical meaning of commutators in quantum mechanics?
At that stage one is fairly comfortable with the concept of wavefunctions and with the Schrödinger equation, and has had some limited exposure to operators. … One common case, for example, is to explain that some operators commute and that this means the corresponding observables are 'compatible' and that there exists a mutual eigenbasis; the commutation relation …
34
votes
11
answers
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Half-integer eigenvalues of orbital angular momentum
Why do we exclude half-integer values of the orbital angular momentum?
It's clear for me that an angular momentum operator can only have integer values or half-integer values. … Of course, when we do the experiments we confirm that a scalar wavefunction and integer spherical harmonics are enough to describe everything. …
28
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2
answers
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Why does the classical Noether charge become the quantum symmetry generator?
It is easy to prove that this is equivalent to $[U,H] = 0$ for all $U$ representing the transformation, where $H$ is the Hamiltonian operator. … Presumably after quantization these can be associated to the Lie algebra generators, acting on wavefunctions on the manifold. Does this sound right to anyone? …
27
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3
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Is there a "position operator" for the "particle on a ring" quantum mechanics model?
For this quantum mechanical system, is there an operator that corresponds to "position" the same way that there are operators corresponding to angular momentum and energy? … My first guess for what the operator would be is
$$
\hat \Phi \big[ \psi(\phi) \big] = \phi \, \psi(\phi)
$$
which would be analogous to the position operator for the "particle in a box" system, but I …
27
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2
answers
2k
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Is there any theorem that suggests that QM+SR has to be an operator theory?
In wave-function theories we have differential operators (e.g., $-i\nabla$), but these aren't dynamical, so there is a clear distinction between an operator and a differential operator. … \
\text{operator theory} & (\mathrm{QM.1}) & (\mathrm{QFT.1}) \\
\text{wave-function theory} & (\mathrm{QM.2}) & \quad ?? …
26
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5
answers
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What is the difference between a functional and an operator?
When we define an operator in physics, e.g. the momentum operator as $\hat{p} = i \frac{d}{dx}$, it is said this operator acts on the wave functions. … Why do we call $\hat{p}$ momentum operator and not momentum functional? …
26
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7
answers
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Is the Momentum Operator a Postulate?
One thing that I haven't been able to derive from them, however, is the identity of the momentum operator. … I know that it makes sense, as it results in the Ehrenfest Theorem, the De Broglie wavelength hypothesis, the Heisenberg Uncertainty Principle (for $x$ and $p$), the momentum operator being the generator …
25
votes
3
answers
3k
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The Origins of the Second Quantization
We all we told that to some extent it makes sense to treat the particle as a Gaussian wave packet. … After the measurement, the wave function collapses and forgets about both 'separate' Gaussians. …
24
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7
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How does the momentum operator act on state kets?
($|\alpha\rangle$ is a Gaussian wave packet.) … I think my question boils down to: Does the operator $\hat{p}$ act on the basis kets $|x\rangle$ or on their coefficients? …
22
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4
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Applying an operator to a wavefunction vs. a (ket) vector
.$$
However, in class I've also seen operators applied to scalar-valued functions, such as the momentum operator in position space:
$$P = - i \hbar \frac{\partial}{\partial x},\quad P \psi(x) = - i \hbar … On the Wikipedia article "Operator (physics)", under "Linear operators in wave mechanics", I found the following:
$$A \psi(x) = A \langle x | \psi \rangle = \langle x | A | \psi \rangle$$
However, that …
22
votes
1
answer
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What is known about the hydrogen atom in $d$ spatial dimensions?
Can these functions be described as eigenfunctions of $d$-dimensional angular momentum operators, analogous to $L^2$ and $L_z$? If so, what are the eigenvalues? … Is there a reasonable closed form for the $d$-dimensional hydrogenic stationary-state wavefunctions? If not, is there a reasonable (asymptotic) approximation formula? …
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5
answers
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Can the momentum operator have an imaginary expectation value?
I'm making examples of wave functions to incorporate in a QM exam. … I came up with the following wave function, which gives me some troubles:
$$\psi(x,0) = \begin{cases}
A(a-x), & -a \leq x \leq a,\\
0& \text{otherwise}. …
20
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4
answers
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Differences between principles of QM and QFT
Wavefunction fundamentalism. All knowable information about a system is encoded in its wavefunction (ignoring phase and normalization).
Unitary evolution of the wavefunction. … The wavefunction evolves over time in a deterministic and unitary manner.
Observables. Any observable is represented by a Hermitian operator.
Inner product. …
19
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3
answers
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Paradox of wavefunction collapse into an unphysical state
For example, we know that the eigenfunctions of the momentum operator (in 1D for simplicity)
$$\hat p = -i \hbar \frac{\partial}{\partial x}$$
are plane waves:
$$\psi_p(x) = A e^{ipx/\hbar}$$
These eigenfunctions … If we try to apply the cited postulate to the momentum operator, we would therefore incur in a contradiction: the system cannot jump into an eigenstate of the momentum operator, because such an eigenstate …
18
votes
2
answers
2k
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Is the Uncertainty Principle valid for information about the past?
My layman understanding of the Uncertainty Principle is that you can't determine the both the position and momentum of a particle at the same point in time, because measuring one variable changes the other …