it is postulated that a perpendicular force can not do work
A force that is perpendicular to the velocity of an object’s center of mass cannot do work on a point particle. However a perpendicular force certainly can do work on non point particle objects, including atoms. When such a force does work the energy increases some other degree of freedom besides the KE of the center of mass.
Note: if an object is treated as a collection of point masses then the point mass where the force is applied does not generally share the velocity of the center of mass. Thus work can be done by the force.
Note 2: Also, if a force is treated as an instantaneous impulse then the instantaneous force is infinite and it can do work even when oriented perpendicular to the velocity. Consider, for example, a object moving along the x axis and an impulsive force in the y direction. The rate of work is $\vec F \cdot \vec v = (0,\infty,0)\cdot (v,0,0)=(0,\infty 0, 0)$. Notice that this includes the mathematically indeterminate form $\infty 0$ which cannot be evaluated directly and must be determined through some other means. Usually we use conservation of momentum and integrate over the impulsive force.