Let us say, for simplicity, that the car is moving by inertia (no force acting on it). Well, not totally, because it is inevitable that, while it moves in a straight line, friction with the ground is decelerating it (i.e. reducing its speed). Then you turn the wheels leftward, at which moment friction starts taking another role, it starts changing the car’s direction, which is another form of acceleration. This creates a typical Newton 3rd law pair of forces: the surface of the ground pushes on the car to change its direction, the car pushes on the surface with a force of equal magnitude and opposite direction. But note that these forces are acting on different bodies. To determine what happens to the car, you have to focus on forces acting on the car. It is subject to gravity pushing downward and normal force pushing upward, both of same magnitude but opposite direction, so they cancel out (this is not a Newton pair, because these forces do act on the same object; if they happen to have same magnitude, it is because normal force, when the ground has enough cohesion, is a sort of self-adjusting mechanism that develops as much strength as needed to avoid penetration). So we are left with a single net force acting on the car, which is the friction exerted by the ground against the turned wheels. That is why, as you have shown in your picture, the car is changing its direction. What is your problem though? The car is not turning as much as you would like and so it is sliding out of the road. Which factors cause this effect? Logically, friction is not good enough, there is not enough rugosity; if friction were enormous, that would be the end of it: imagine that, instead of crashing against the small rugosities of the road, the car crashed against big stone balls… The other factor is the car’s velocity: if it were very small, then it would be easier for the ground to create a trap for it…
This formula calculates the maximum velocity that the car can have, given the friction exerted by the road, if you want to keep it moving within the curvature of a given radius described by the road:
$$m\frac{{{v^2}}}{r} = \mu {F_N} = \mu mg \to \frac{{{v^2}}}{r} = \mu g \to {v_{\max }} = \sqrt {\mu gr}
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You can read the formula as stating that friction (which is a coefficient of normal force, which in turn is equal to the car’s weight) is strong enough to act as centripetal force, which is the one given by the expression with m and v and r. But please note that the latter expression is not saying that that the car is being pushed out of the curvature by any force dependent on its mass or its velocity or the radius of curvature. The car just tends to keep its original direction by sheer inertia. The expression is not there because of something that the car does. It is there because we assume that the car is turning around and if this happens, it is because there is enough friction, it just happens that we calculate the value of such friction force by looking at the challenge it was facing (mass and v being two factors that make the challenge harder, radius being another that makes things easier).
Therefore, as you can see, no reference to centrifugal force is really needed to explain what happens.
Now imagine that a passenger inside the car feels that he is being expelled out of it. The safety belt retains him, nevertheless. This can be described from an inertial reference frame, like the ground. In this frame, the passenger, again, just moves by inertia. The force that holds it is the same as the one that makes the car turn, the ground’s friction, which is communicated to him through the belt. Then the passenger pushes back on the belt, just like the car pushes on the road. Still we made no reference to centrifugal force.
But we can also describe things from an accelerated reference frame, like the turning car itself. The nature of any reference frame is that it is motionless and it is others who move. So to account for the fact that the passenger feels something pulling him out of the car, in this peculiar (accelerated) frame you must invent a fictitious force, which is called centrifugal force, and is exactly cancelled by the tension exerted by the belt.
Edit: The term "reactive centrifugal force" is sometimes also used meaning the force exerted by the car on pavement or by the passenger on the safety belt. That is a real force. But don't expect to compare it against the friction force and detect which one is the winner, because by Newton 3rd law they are always equal. Give up with the mindset where you see forces as qualities that objects have and bring to the interaction. Force is a measure of the interaction. Let the car crash against a wall and you will find a strong force, let it slide on ice and there will be almost none. If you still want to see things as a battle, you can, but don't choose the Newton 3rd law pair of forces as the fighters. You must choose forces acting on a single body... and being currently active. You are comparing friction on one side and the historical force that set the car in motion on the other side. But the latter force is not operative. That does not mean it is irrelevant: it indirectly shows up in the form of the inertia of the body (m and v), which is what triggers the interaction and as explained in the answer it has the effect of making the challenge harder for the pavement.