So after I learnt rotational dynamics I understood that the linear velocity is equal to the angular velocity times the radius and if we derive with respect to time, we get the linear/tangential acceleration:
$ a_{t} = \alpha R $
However, after reading about the pure rolling/slipping/skidding cases, I'm not sure I understand if the previous equation is valid for all three cases.
My logic is that if the ball spins faster (or slower) then it moves, i.e. not pure rolling:
$ v_{cm} \neq \omega R $
Therefore:
$ a_{cm} \neq \alpha R $
And
$ a_{t} \neq a_{cm} $