The simple answer to your question is Yes. You can create 51/49 polarization, or 52/48 polarization, or whatever mixture you might care to produce.
This can easily be seen in production of Type I entangled photon pairs. For this type, 2 BBo crystals are used. Each thin crystal generates VV pairs that are not polarization entangled. They are placed in line with each other, but one is rotated 90 degrees relative to the other so it is producing HH pairs. When down conversion occurs, it can have occurred from either crystal. You won’t know which though. This places the output in a 50/50 superposition of VV>+HH> which is fully entangled. See figure 1.a. in either of the following papers by Kwiat et al:
https://arxiv.org/pdf/quant-ph/9810003
https://arxiv.org/pdf/1001.4182
So far so good. Now, if the 2 crystals are oriented say 75 degrees relative to each other (instead of 90 degrees), they will produce pairs that are distinctly more VV> than HH>. They will be polarization entangled, but not maximally so. By suitable rotation, you can achieve the desired mixture.
However: as you dial the mixture away from 50/50, the entanglement quality changes accordingly.
Edited to add/clarify: Alice cannot do anything to A to change the marginal probability that Bob sees for his B photons. That is strictly a function of how the initial pairs are created.