The positively charged ions migrate toward grids that contain thousands of very precisely aligned holes (apertures) at the aft end of the ion thruster. The first grid is the positively charged electrode (screen grid). A very high positive voltage is applied to the screen grid, but it is configured to force the discharge plasma to reside at a high voltage. As ions pass between the grids, they are accelerated toward a negatively charged electrode (the accelerator grid) to very high speeds (up to 90,000 mph).
Taken from NASA website about ion thruster.
How could positively charged ion pass through negatively charged electrode (the accelerator grid) without sticking to the electrode.