I was wondering if pure superposition states can be created thermally. Are only energy eigenstates occupied when we provide heat or are superposition states also a part of the statistical mix of states of a system in thermal equilibrium, proportional to a weight, based on their energy expectation value ?
Is for example a superposition state $|\psi\rangle =\frac{1}{\sqrt2}(|n_1\rangle +|n_2\rangle ) $ with energy expectation value $ \langle E\rangle_\psi = (E_1+E_2)/2 $ found with a probability of $p_\psi = e^{\beta \langle E\rangle _\psi}/Z$ or is it not part of a thermal ensemble ?