Consider a system of two particles $\alpha$ and $\beta$ each with spin 1/2. They are in the same real three di-mensional space. We rotate the system in this space so each particle by the same rotation, that is $R_{1z}\equiv R_{2z}$.
The rotation in the 2-dimensional Hilbert space $\mathcal H_{\rho}\:(\rho=\alpha,\beta)$ of each particle is represented by a special unitary operator
\begin{equation}
{{^{\bf 2}}}U_{\alpha}= {^{\bf 2}}U={^{\bf 2}}U_{\beta} \in SU(2)
\tag{01}\label{01}
\end{equation}
so by the special unitary operator
\begin{equation}
{^{\bf 4}}U={^{\bf 2}} U_{\alpha}\otimes {^{\bf 2}}U_{\beta}= {^{\bf 2}}U\otimes {^{\bf 2}}U \in SU(4)
\tag{02}\label{02}
\end{equation}
in the product 4-dimensional Hilbert space $\mathcal H=\mathcal H_{\alpha}\otimes \mathcal H_{\beta}$.
For what next see $\:\color{blue}{\textbf{Example A}}\:$ in my answer here What is the symmetry of the pion triplet (π−,π0,π+)?.
So try this : Represent the particle states by $\:2\times 1\:$ matrices
\begin{equation}
\uparrow_z =
\begin{bmatrix}
\:1\:\vphantom{\dfrac12}\\
\:0\:\vphantom{\dfrac12}
\end{bmatrix}
\qquad
\downarrow_z =
\begin{bmatrix}
\:0\:\vphantom{\dfrac12}\\
\:1\:\vphantom{\dfrac12}
\end{bmatrix}
\tag{03}\label{03}
\end{equation}
Express the product singlet state as $\:4\times 1\:$ matrix
\begin{equation}
|\boldsymbol{1}\rangle =\uparrow_z\downarrow_z-\downarrow_z\uparrow_z =
\begin{bmatrix}
\:1\:\vphantom{\dfrac12}\\
\:0\:\vphantom{\dfrac12}
\end{bmatrix}
\otimes
\begin{bmatrix}
\:0\:\vphantom{\dfrac12}\\
\:1\:\vphantom{\dfrac12}
\end{bmatrix}
-
\begin{bmatrix}
\:0\:\vphantom{\dfrac12}\\
\:1\:\vphantom{\dfrac12}
\end{bmatrix}
\otimes
\begin{bmatrix}
\:1\:\vphantom{\dfrac12}\\
\:0\:\vphantom{\dfrac12}
\end{bmatrix}
=
\begin{bmatrix}
\:0\:\vphantom{\tfrac{a}{b}}\\
\:1\:\vphantom{\tfrac{a}{b}}\\
\:0\:\vphantom{\tfrac{a}{b}}\\
\:0\:\vphantom{\tfrac{a}{b}}
\end{bmatrix}
-
\begin{bmatrix}
\:0\:\vphantom{\tfrac{a}{b}}\\
\:0\:\vphantom{\tfrac{a}{b}}\\
\:1\:\vphantom{\tfrac{a}{b}}\\
\:0\:\vphantom{\tfrac{a}{b}}
\end{bmatrix}
\tag{04}\label{04}
\end{equation}
that is
\begin{equation}
|\boldsymbol{1}\rangle = \uparrow_z\downarrow_z-\downarrow_z\uparrow_z =
\begin{bmatrix}
\hphantom{-}0\hphantom{-}\vphantom{\tfrac{a}{b}}\\
+1\hphantom{-}\vphantom{\tfrac{a}{b}}\\
-1\hphantom{-}\vphantom{\tfrac{a}{b}}\\
\hphantom{-}0\hphantom{-}\vphantom{\tfrac{a}{b}}
\end{bmatrix}
\tag{05}\label{05}
\end{equation}
Represent the rotation by a $\:2\times 2\:$ special unitary matrix
\begin{equation}
{^{\bf 2}}U =
\begin{bmatrix}
\:\hphantom{-}g & \hphantom{-}h\:\vphantom{\dfrac12}\\
\:-\overline{h} & \hphantom{-}\overline{g}\:\vphantom{\dfrac12}
\end{bmatrix}
\qquad
g\overline{g}+h\overline{h}=1
\tag{06}\label{06}
\end{equation}
and find the $\:4\times 4\:$ special unitary matrix in the product space, see equation \eqref{02}
\begin{equation}
{^{\bf 4}}U={^{\bf 2}}U\otimes {^{\bf 2}}U=\left({^{\bf 2}}U\right)^{\otimes 2} \in SU(4)
\tag{07}\label{07}
\end{equation}
Then find what is the result of the application of $\:{^{\bf 4}}U\:$ on the singlet $\:|\boldsymbol{1}\rangle\:$
\begin{equation}
{^{\bf 4}}U|\boldsymbol{1}\rangle = ???
\tag{08}\label{08}
\end{equation}
Alternatively, due to the fact that the factor spaces $\mathcal H_{\alpha},\mathcal H_{\beta}$ are of the same dimension $\:2$ we could represent the product states as $\:2\times 2\:$ matrices. Especially for the singlet we have
\begin{equation}
|\psi\rangle =\uparrow_z\downarrow_z-\downarrow_z\uparrow_z =
\begin{bmatrix}
\:1\:\vphantom{\dfrac12}\\
\:0\:\vphantom{\dfrac12}
\end{bmatrix}
\begin{bmatrix}
\:0\:& 1\vphantom{\dfrac12}
\end{bmatrix}
-
\begin{bmatrix}
\:0\:\vphantom{\dfrac12}\\
\:1\:\vphantom{\dfrac12}
\end{bmatrix}
\begin{bmatrix}
\:1\:& 0\vphantom{\dfrac12}
\end{bmatrix}
=
\begin{bmatrix}
\:\:0\:&\:1\:\: \vphantom{\dfrac12}\\
\:0\:&\:0\:\: \vphantom{\dfrac12}
\end{bmatrix}
-
\begin{bmatrix}
\:\:0\:&\:0\:\: \vphantom{\dfrac12}\\
\:1\:&\:0\:\: \vphantom{\dfrac12}
\end{bmatrix}
\tag{09}\label{09}
\end{equation}
that is
\begin{equation}
|\psi\rangle =\uparrow_z\downarrow_z-\downarrow_z\uparrow_z =
\begin{bmatrix}
\hphantom{-}0\:& +1\:\: \vphantom{\dfrac12}\\
-1\:&\hphantom{+}0\:\: \vphantom{\dfrac12}
\end{bmatrix}
\tag{10}\label{10}
\end{equation}
Then using the special unitary matrix $\:{^{\bf 2}}U\:$ of \eqref{06} find the product state represented by the following $\:2\times 2\:$ matrix
\begin{equation}
\left({^{\bf 2}}U\right)|\psi\rangle\left({^{\bf 2}}U\right)^{\boldsymbol{\top}} =\left({^{\bf 2}}U\right)\left(\uparrow_z\downarrow_z-\downarrow_z\uparrow_z\!\!\vphantom{\tfrac12}\right)\left({^{\bf 2}}U\right)^{\boldsymbol{\top}}
\tag{11}\label{11}
\end{equation}
where $\:\left({^{\bf 2}}U\right)^{\boldsymbol{\top}}\:$ the transpose of $\:\left({^{\bf 2}}U\right)$.