The proof turns out to be very simple. Both Farcher and npojo have essentially answered the question but I’m going to present a detailed explanation, if only for my own satisfaction. This also captures elements of a discussion on the subject in the physics problem solving chat room.
There are a couple of preliminaries to get out of the way. Start by considering a single plate with a charge per unit area of $Q$.
The plate is a conductor so we know that:
a) the charge goes to the surfaces
b) the field inside the plate is zero
Since the charge resides at the surfaces we effectively have two sheet charges that I've shown in red and blue. The fields produced by these two sheets of charge are going to be approximately the infinite charged sheet field $E = Q/(2\epsilon)$. If the charge on the left side is $x$ then the charge on the right side has to be $Q-x$ so:
$$\begin{align}
E_a &= \frac{x}{2\epsilon} \\
E_b &= \frac{Q-x}{2\epsilon}
\end{align}$$
At the point $P$ inside the plate the field is zero, because we are inside a conductor, so the two fields $E_a$ and $E_b$ must be equal and opposite. Equating the fields immediately tells us that $x=Q/2$ and therefore that the charges on the two surfaces are equal to $Q/2$ (which should surprise no-one).
One more preliminary: consider any pair of adjacent plates in our system:
The blue line shows a Gaussian surface. The field inside the (conducting) plates is zero, so assuming the plates are large enough for end corrections to be negligible the flux through the surface is zero and hence the total charge inside the surface must be zero. That means $q_1 = -q_2$ i.e. the charges on the adjacent surfaces are equal and opposite. Again this is kind of obvious but it’s worth stating explicitly as we’ll need it for the proof.
Now to business. To see how the proof works start with a system of two plates with charges $Q_1$ and $Q_2$:
Again set the charge on the left surface of the first plate to $x$, and then the charges on the rest of the surfaces follow. As with the single plate we started with the field at $P$ is zero because it’s inside a conductor, and that means $E_{1a}$ must be equal and opposite to the sum of all the other fields:
$$ E_{1a} = E_{1b} + E_{2a} + E_{2b} $$
And substituting for the fields:
$$ \frac{x}{2\epsilon} = \left(\frac{Q_1-x}{2\epsilon} - \frac{Q_1-x}{2\epsilon}\right) + \frac{Q_2 + Q_1 - x}{2\epsilon} $$
I've bracketed the two terms that cancel. They cancel because the charges on adjacent surfaces are equal and opposite to their contributions to the total field at $P$ are equal and opposite. We end up with:
$$ x = \frac{ Q_2 + Q_1}{2} $$
And therefore the charges on the leftmost surface and the rightmost surface are both $(Q_1+Q_2)/2$ and we’ve proved the outermost charges are equal.
And the extension to $n$ plates is straightforward. The key point is that the fields on adjacent surfaces are all going to cancel so only the fields due to the leftmost and rightmost fields matter. The charges on the plates are:
Starting with a charge $x$ on the leftmost plates the charges on the right facing (blue) sides are $Q_1-x$, $Q_1+Q_2-x$, $Q_1+Q_2+Q_3-x$ and so on up to the rightmost surface and that has the charge $Q_1 + … + Q_n – x$. When we add up all the fields at the point $P$ the fields due to each adjacent sheet of charge cancel and we end up with:
$$ x = \tfrac{1}{2}\sum_n Q_i $$
So the charges on the outermost plates both have the same value of $\tfrac{1}{2}\sum_n Q_i$ and we've proved the result we wanted.