There are questions that may seem to be similar to this one, but I've yet to find an answer.
I have come to understand that a flat universe, that is to say a curverature of $k=0$ which means that $S_k(r) = r$. The FLRW metric polar coordinates: $$ds^2 = -dt^2 + a^2(t) \left[ \frac{dr^2}{1 - kr^2} + r^2d\Omega^2 \right]$$ Now, since only $r$ is being altered, $dt = 0$ and $d\Omega$ = $0$. $$ds^2 = a^2(t) \frac{dr^2}{1 - kr^2}$$ This can be integrated to: $$s(r) = \frac{\sin^{-1}(\sqrt{k}r)}{\sqrt{k}}$$ So, by definition, the maximum value is when $\sin^{-1} = 90^\circ = \frac{\pi}{2}$ which occurs when $\sqrt kr=1$ To find the highest value, we replace $\sin^{-1}(\sqrt kr)$ with $\pi \over 2$ and get: $$s(r)_{\text max} = \frac{\pi}{2\sqrt k}$$ Therefore, as $k \to 0,\space s(r)\to \infty$. Given $k=0$, there is an infinite possible distance.
Now that we have that out of the way, when physicists talk about the size of the universe, by which I mean "when the universe was the size of a grapefruit" r a similar comparisson, space must have still been infinite, so what is this a description of?