Let's take a heavy atom (since velocity of electron is high in it) and project it with relativistic velocity. So the electron revolving around the nucleus in partial particle - wave character can have velocities in direction of motion of particle, opposite to it and in between.
So these will lead to fluctuations in the relativistic mass of the electron, it being higher on one side lower on the other. Will this mass difference lead to any changes in properties (permanent or temporary)?