Let's say we irradiate a metal with a photon beam whose energy per quanta is 10 times the work function of the metal, say 10(k). So post absorption it will have the same energy, and say it collides with another metal atom in its lattice such that it transfers 4k energy to the other atom and still posses 6k, again we assume that they must've collided with other atoms and by the time they reach the metal surface they have energy 4k and 3k respectively( solely made up just to imply that their energies are more than the work function). Now both possess the energy to break free and will do so. Therefore one photon ended up energizing and emitting two electrons indirectly.
Kindly correct me wherever I am wrong.