Scenario 1:
Here, $P>Q$. $O$ is the center of mass of the rigid and uniform bar/stick. The resultant acts to the right of $\vec{P}$ as $P>Q$.
Scenario 2:
Here, $P>Q$ also. $O$ is the center of mass of the rigid and uniform bar/stick. Now, the problem here is that as $\vec{P}$ and $\vec{Q}$ act at the two ends of the bar/stick, there is no place left to the right of $\vec{P}$. So, where will the resultant of magnitude $(P-Q)$ act?