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DO NOT USE THIS TAG just because your question involves math! If your question is on simplification of a mathematical expression, please ask it at math.stackexchange.com The mathematics tag covers non-applied pure mathematical disciplines that are traditionally not part of the mathematical physics curriculum, such as, e.g., number theory, category theory, algebraic geometry, general topology, algebraic topology, etc.

3 votes
3 answers
322 views

Why heat is extensive quantity?

Question. Why heat is an extensive quantity? That is, why heat is proportional to mass? I am interested in an answer based on classical thermodynamics. I am asking to help me fill the gaps in my argum …
Alex Alex's user avatar
  • 321
-1 votes
2 answers
353 views

Making equal arguments of sine or cosine function

I have trouble understanding one common type of inference about waves. In physics textbooks, frequently when text is about waves I see inference where arguments of trigonometric functions made equal k …
Alex Alex's user avatar
  • 321
0 votes
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Prove $G=U+PV-TS+\sum \mu_i n_i$

According to Bazarovs Thermodynamics textbook in case when state of state of system is determined by generalized forces $A_i$ and conjugated outer parameters $a_i$ then (generalized) Gibbs energy is …
Alex Alex's user avatar
  • 321
1 vote
2 answers
149 views

Two total differentials with equal variable differentials. Why coefficients in front of diff...

Could you prove that inference like that is valid: $$(1) \left\{ \begin{array}{c} dU=T dS-pdV \\ dU=\frac{\partial U}{\partial S}dS+ \frac{\partial U}{\partial V} dV \end{array} \right. \implies \le …
Alex Alex's user avatar
  • 321
-2 votes
1 answer
320 views

Prove $G=U+PV-TS+\sum \mu_i n_i$

Question. I have trouble understanding one step in Gibbs adsorption isotherm derivation. I don't understand why we can write $G=U+PV-TS+\sum \mu_i n_i$, how to prove this equation? I saw this equation …
Alex Alex's user avatar
  • 321
-2 votes
5 answers
353 views

Separatibility of wave-function in Schrodinger equation describing motion of particle in sph... [closed]

Question. Why wave-function describing rotation of particle around spherical surface is separable? Why solution obtained assuming function is separable is general solution? I am interested in proof of …
Alex Alex's user avatar
  • 321