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I understand that the Schrodinger Equation for the hydrogen atom is

$$E\Psi=-\frac{\hbar^2}{2m}\nabla^2\Psi+V\Psi$$

with $$-\frac{\hbar^2}{2m}\nabla^2\Psi+V\Psi$$ being the Hamiltonian

and I understand that the Hamiltonian of the Helium Atom is

$$-\frac{\hbar^2}{2m}\left(\nabla_1^2\Psi+\nabla_2^2\Psi\right)+V_1\Psi+V_2\Psi+V_{12}\Psi$$

although I haven't seen what's on the other side of the equation

As I understand it each electron can also be in a different energy level from the other

So is the non relativistic differential equation for the Helium atom

$$E_1\Psi+E_2\Psi=-\frac{\hbar^2}{2m}\left(\nabla_1^2\Psi+\nabla_2^2\Psi\right)+V_1\Psi+V_2\Psi+V_{12}\Psi$$

or is it something else?

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1 Answer 1

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Not sure what $E_1 + E_2$ are supposed to be - probably there is no such separation into a sum (and the last equation is missing a wavefunction) - but generally, well, you're right, the time-independent Schrödinger equation for a system (including the Helium atom) is the eigenvalue equation $$ E \Psi = \widehat{H}\Psi $$ for the energy $E$ of the system described by the wavefunction $\Psi$ and with the Hamiltonian operator $\widehat{H}$.

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  • $\begingroup$ I did forget to add the wavefunction to the left of the last equation, so i added it now. Thanks for pointing that out. $\endgroup$ Commented Apr 3, 2022 at 16:55
  • $\begingroup$ Also I know that I can't do $\Psi(r_1,\theta_1,\phi_1,r_2,\theta_2,\phi_2)=\Psi(r_1,\theta_1,\phi_1)\Psi(r_2,\theta_2,\phi_2)$ because there's a $V(r_1,r_2)$ but would doing something like $\Psi(r_1,\theta_1,\phi_1,r_2,\theta_2,\phi_2)=A_1(r_1,\theta_1,\phi_1,r_2,\theta_2,\phi_2)A_2(r_1,\theta_1,\phi_1,r_2,\theta_2,\phi_2)$ be useful? $\endgroup$ Commented Apr 3, 2022 at 17:09
  • $\begingroup$ No. What for and how? The separation ansatz reduces complexity of the problem, you suggestion does not. $\endgroup$
    – kricheli
    Commented Apr 3, 2022 at 18:47
  • $\begingroup$ The idea I have for $A_1$ and $A_2$ is to approximate the function $A_1$ at each $(r_2,\theta_2,\phi_2)$, and approximate the function $A_2$ at each $(r_1,\theta_1,\phi_1)$ $\endgroup$ Commented Apr 3, 2022 at 21:59

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