You can see this in two ways:
From the Potential: Consider that the electrostatic potential is a scalar field. It therefore necessarily has a single, well-defined, gradient at each point, which determines the direction of the electric field. It is therefore impossible for there to be two electric fields at a point. While you can decompose the electric field at the point into two vectors (or 20 vectors, or whatever), those are not the physical electric field, which is only one. So since the electric field is perpendicular to the equipotential line, the fact that there is a single field (gradient direction) implies there can be only one direction to the equipotential line at that point (the direction perpendicular to the gradient).
The only exception is if there is a region/point with no gradient. A level-plane surface. In this region the field will be zero, and talking about equipotential lines makes no sense.
From the field: There is one value for the electric force at a point, and therefore for the electric field at that point. Because the divergence of the electric field is zero (Maxwell's equations), this electric field must be the divergence of a scalar field, which we call the "electrostatic potential". And then continue as above.
Whichever you deem to "really exist" - the electric field, or the electrostatic potential - it follows that at every point the field is the gradient of the potential, and hence is perpendicular to its equipotential lines (the perpendicular direction to the gradient) and hence two such lines cannot cross. Except in a region where there is no gradient at all, and hence no field and no equipotential lines.