It's the beamsplitter unitary (a.k.a. the QFT in two dimensions, a.k.a. the Hadamard gate), represented via its action on two-mode Fermion states.
With two modes, there are four possible fermionic states: $|11\rangle\equiv c_1^\dagger c_2^\dagger |\text{vac}\rangle$ (one fermion per mode), $|01\rangle\equiv c_2^\dagger |\text{vac}\rangle$ (a fermion in the second mode), $|10\rangle\equiv c_1^\dagger |\text{vac}\rangle$ (a fermion in the first mode), and $|00\rangle\equiv|\text{vac}\rangle$ (no fermion at all).
A beamsplitter will act on these states as follows:
\begin{align}
|00\rangle &\to |00\rangle, \\
|10\rangle &\to \frac{1}{\sqrt2}(|10\rangle+ |01\rangle), \\
|01\rangle &\to \frac{1}{\sqrt2}(|10\rangle- |01\rangle), \\
|11\rangle &\to -|11\rangle.
\end{align}
To see this you just need to consider that the beamsplitter acts on the fermionic modes as
$$c_1^\dagger\to\frac{1}{\sqrt2}(c_1^\dagger+c_2^\dagger),
\qquad
c_2^\dagger\to\frac{1}{\sqrt2}(c_1^\dagger-c_2^\dagger),$$
so that for example
$$|11\rangle\equiv c_1^\dagger c_2^\dagger |\text{vac}\rangle
\to \frac12(c_1^\dagger+c_2^\dagger)(c_1^\dagger-c_2^\dagger)|\text{vac}\rangle
\to -c_1^\dagger c_2^\dagger|\text{vac}\rangle.$$
The rest of the rules is similarly derived. The matrix reported in the paper is simply the matrix representation of these rules.
This is a special case of a more general problem: given a unitary $U$, how does it act on many-fermion states?
The general result is that the scattering amplitude between an $n$-fermion, $m$-mode input $$|r_1,...,r_m\rangle\equiv c_1^{r_1\dagger}\cdots c_n^{r_n \dagger}|\text{vac}\rangle$$ and an output $|s_1,...,s_m\rangle$ is given by the determinant of the matrix obtained from $U$ by taking its first column $r_1$ times, its second column $r_2$ times, etc., and similarly taking rows according to the occupation numbers in $|s_1,...,s_m\rangle$.
For example, applying this to the above case with $U=H$ and $|r_1,r_2\rangle=|11\rangle$, we get that the probability amplitude of $|11\rangle$ evolving into $|11\rangle$ is the determinant of $H$ itself, which is $-1$, consistently with what we found by direct analysis before.