Let us start from $\textbf{B}=\nabla \times \textbf{A}$ and write its components $B_k=\epsilon_{ijk}\partial_i A_j$.
I want to show that $\partial_i A_j - \partial_j A_i = \epsilon_{ijk}B_k$. I can sense that it works, but I want to see it directly. How should I start?