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When deriving the Density of States for a Free Electron Fermi Gas, Kittel seems to flamboyantly interchange $\epsilon$ and $\epsilon_F$ when going between equations. I am specifically puzzled as to why he is allowed to do that when going from equations 17 to 19 at page 140 in the eigth edition. Any reason as to why that is allowed?

The equations at hand are:

$ \epsilon_F = \frac{\hbar^2}{2m}\left(\frac{3\pi^2 N}{V} \right)^{2/3}$ (17)

and:

$N = \frac{V}{3\pi^2}\left( \frac{2m \epsilon }{\hbar^2} \right)^{3/2}$ (19)

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  • $\begingroup$ Could you post the relevant equations for those without the book on hand? $\endgroup$
    – jacob1729
    Commented Apr 22, 2019 at 16:30
  • $\begingroup$ Yes, I will update the post for easy readability. $\endgroup$ Commented Apr 22, 2019 at 16:41
  • $\begingroup$ Looks like a typo to me $\endgroup$
    – jacob1729
    Commented Apr 22, 2019 at 17:28
  • $\begingroup$ I don't think it is. $\epsilon_F$ is the fermi energy, while $\epsilon$ would be any orbital energy equal to or less than the fermi energy. $\endgroup$ Commented Apr 22, 2019 at 17:30

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It is a typo, and I think I can explain how it appeared. I don't have the eighth edition, but in my older copy, close after these expressions is an expression for the density of states, ${\cal D}(\epsilon)$, $${\cal D}(\epsilon)=\frac{V}{2\pi^{2}}\left(\frac{2m}{\hbar}\right)^{3/2}\epsilon^{1/2}.$$ In the expression for ${\cal D}(\epsilon)$, it really is $\epsilon$ (the energy of an arbitrary single-particle state), not the Fermi energy $\epsilon_{F}$. I think the similarity of the two expressions led to the subscript on "$\epsilon$" being dropped in the formula for $N$.

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