The distinction between quantum fields and classical trajectories arises from the different scales at which we observe and describe physical phenomena. In quantum field theory (QFT), both electromagnetic fields and matter are represented as quantum fields, as you correctly pointed out. However, the classical limit of these fields manifests differently due to their intrinsic properties and the way they interact with the environment.
The electromagnetic field, represented by A^μ in QFT, retains its field-like nature in the classical limit because it is a bosonic field with long-range interactions. This allows for coherent superpositions of many photons, leading to classical wave-like behavior even at macroscopic scales.
On the other hand, the fermionic field ψ, which represents matter particles like electrons, behaves differently in the classical limit. Fermions obey the Pauli exclusion principle, which prevents them from occupying the same quantum state. This property, combined with the process of decoherence, leads to the localization of fermions and the emergence of classical particle-like behavior at macroscopic scales.
The transition from quantum fields to classical trajectories for matter particles is not a fundamental distinction but rather a consequence of our observational scale and the interactions with the environment. As Einstein noted, "Guided by purely formal points of view, H. A. Lorentz was the first to introduce the hypothesis" of treating electrons as rigid bodies with classical trajectories. This approximation works well for many practical purposes but breaks down when quantum effects become significant.
Regarding your specific questions:
The reason for the different classical treatments of electromagnetic and matter fields is rooted in their quantum properties and how they interact with the environment. The coherent nature of bosonic fields allows for classical field descriptions, while the exclusion principle and decoherence lead to particle-like behavior for fermions at classical scales.
Treating the Dirac equation as a classical field equation can indeed yield useful results in certain situations. For instance, in the study of plasmas or electron beams, a statistical description based on the classical Dirac field can provide insights into collective behavior and wave-like phenomena of electron ensembles. This approach bridges the gap between fully quantum and purely classical descriptions, allowing for a more nuanced understanding of electron dynamics in intermediate regimes.
It's worth noting that the development of quantum electrodynamics (QED) and the standard model of particle physics has shown that all fundamental particles, including electrons, are best described as excitations of quantum fields. The classical trajectory description is an approximation that emerges under certain conditions.