I learned recently that if you have the Dirac spinor represented in the Weyl (chiral) basis $\Psi = \begin{pmatrix} \psi_L \\ \psi_R \end{pmatrix}$, then given a Lorentz Transformation $\Lambda = exp[\frac{1}{2}\Omega_{\rho \sigma}M^{\rho\sigma}]$, the corresponding transformation $S[\Lambda]$ for $\Psi \rightarrow S[\Lambda]\Psi$ looks like $S[\Lambda] = exp[\frac{1}{2}\Omega_{\rho \sigma}S^{\rho\sigma}]$. In the chiral basis, this looks like each of the $\psi_L$ and $\psi_R$ transforming as the different spin-1/2 representations of $so(3,1)$.
Here, the $so(3,1)$ Lie algebra is represented by the standard Lorentz matrices $M^{\rho\sigma}$ for the $x^\mu$ transformation, and the other matrices $S^{\rho\sigma}$ are the algebra generated by the gamma matrices $S^{\rho\sigma} = \frac{1}{4}[\gamma^\rho,\gamma^\sigma]$.
My question is (in probably imprecise phrasing), is it possible to choose $\gamma^\mu$ to be 8x8 matrices in such a way that $S^{\rho\sigma} = \frac{1}{4}[\gamma^\rho,\gamma^\sigma] = M^{\rho\sigma} \oplus M^{\rho\sigma} $? i.e. can we pick $\gamma^\mu$ so that the chiral components $\psi_L, \psi_R$ each transform like 4-vectors would?