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So, first of I would like to apologize if my question is at all stupid, I am not at all good at physics, but I do quite enjoy studying and learning about it.

So I know about refraction, I'm aware of Snell's law (though I don't understand how it was derived), and I have heard the ever-popular soldiers marching until they meet a hill analogy. The issue I have with this analogy is that when the soldiers, representing molecules or particles, are put out of alignment due to some of them being slowed down before others, they compensate by changing the angle that they are going. With soldiers fine, because soldiers have a brain and can make a conscious choice to change direction to stay in alignment, but molecules don't have brains to make that change in direction. I guess what I am trying to ask, is why do particles change direction instead of just slowing and falling out of sink with each other?

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  • $\begingroup$ If a particle does onething wouldn't all the others do the same because they are the same particle! $\endgroup$ Commented Jan 31, 2017 at 7:43
  • $\begingroup$ They aren't one particle, they are a bunch of particles of the medium that make up the wave. The particles move straight forward until they go through a different medium. If they are at an angle, some particles will be slowed down before others, changing the angle of that row of particles, but I don't understand how the particles of waves are "attached to each other" and why they change their angle to compensate. Shouldn't the particles just continue straight forwards and get all jumbled up? Like soldiers falling out of rank, because they don't have brains to change directions. $\endgroup$
    – N.D.H.
    Commented Jan 31, 2017 at 18:54
  • $\begingroup$ The waveform is treated as one physical thing, like, using another analogy, a car that's driving onto a different surface and winds up turning. What I don't get is why waves have this tendency to stick together; a car is solid and the whole thing is effected by forces on part of it. Because particles of some medium are not physically bound, but move in a group as a wave, shouldn't one side of the wave be delayed before the other side (changing the particles are lined up with each other) but the particles continue forwards in the direction they were going? $\endgroup$
    – N.D.H.
    Commented Jan 31, 2017 at 19:03
  • $\begingroup$ Great question, don’t let anyone discourage you from asking questions about individual photons. You are correct the marching soldier analogy is incomplete. Try picturing a photon entering a glass surface at no angle and then being pulled equally side to side by the atoms as it passes through. When a photon approaches at an angle, one side of the photon is closer to the surface and pulled that way but as soon as it enters its equally pulled side to side. The more the angle the more it’s pulled before entering. The same thing happens as they exit the other side. $\endgroup$ Commented Feb 21, 2020 at 16:25

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I prefer to understand this question in terms of the electric fields. Basically, Snell's law falls out of forcing phase matching at the interface.

First of all, when you talk of a light ray, I'll take that to mean a plane wave of a specific frequency and direction. Consider the problem of a plane wave approaching an interface at $x=0$ from the $-x$ half-space, so traveling generally in the $+x$ direction, but at an angle $\theta_1$ from normal. The left half-space, $x<0$ contains a material of refractive index $n_1$, and the right half-space contains a material of refractive index $n_2$. We'll assume that the electric field is polarized in the $z$-direction, and only consider the $z$-component of the electric field. This electric field can be given by

$E_1(x,y,t) = \cos(k_1 x \cos(\theta_1) + k_1 y \sin(\theta_1) - \omega t) \hspace{1cm} x \lt 0$

where $\omega = 2\pi f$ is the radial frequency, $k_1 = \frac{\omega n_1}{c}$ is the propagation constant in that medium, and $c$ is the speed of light.

In the right half-space, $x>0$, the transmitted wave will look like

$E_2(x,y,t) = A \cos(k_2 x \cos(\theta_2) + k_2 y \sin(\theta_2) - \omega t + \phi) \hspace{1cm} x\gt 0$

where $k_2 = \frac{\omega n_2}{c}$ and and $\theta_2$ is the unknown transmitted angle. $A$ is an as-yet-unknown magnitude, $\phi$ is some unknown phase offset. $A$ and $\phi$ are only included to be complete, as we will quickly find that $A=1$ and $\phi=0$.

One of the first things you learn in introductory electromagnetics is that the tangential component of the electric field must be continuous everywhere, even across material discontinuities. (Unless there's some kind of source, which we're assuming there's not.) The z-component of $\mathbf{E}$ is clearly tangential to the interface. That means that we must find that

$E_1(x,y,t)|_{x=0} = E_2(x,y,t)|_{x=0}$

$\cos(k_1 y \sin(\theta_1) - \omega t) = A \cos(k_2 y \sin(\theta_2) - \omega t + \phi)$

It should be apparent that the left and right side of this equation can only be equal for all $y$ and $t$ if $A=1$, $\phi=0$, and

$k_1 \sin(\theta_1) = k_2 \sin(\theta_2)$

$\frac{\omega n_1}{c} \sin(\theta_1) = \frac{\omega n_2}{c} \sin(\theta_2)$

$n_1 \sin(\theta_1) = n_2 \sin(\theta_2)$


This figure shows a graphical depiction when $n_1 < n_2$. Note that the fields match at $x=0$.

Graphical depiction of Snell's law via phase-matching of plane waves

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