Neutron stars form in core collapse supernovae, and have progenitors that are of at least $8M_{\odot}$.
Stars like the Sun are found in binary systems about half of the time - to be more precise, if you look at Sun-like stars it turns out that about 50% of the time you are looking at a multiple system, where the Sun-like star is the most massive component. Another statistic that can be quoted is that 2/3 of Sun-like stars are in some sort of multiple system with another star. But more massive stars are found more frequently in binary or multiple systems. The literature is reviewed by Duchene & Kraus (2013); they conclude that an early-B or O-star ($>8M_{\odot}$) is born (on average) with $\geq 1$ companions, and some have argued that O-stars are always born in binary/multiple systems.
In terms of what the companion masses are, the review of Duchene & Kraus concludes that the distribution of mass ratios $f(q)$ is flat (ie. all masses are equally probable), or possibly favours lower mass ratios ($q<0.5$). The frequency of $q<0.1$ companions is still unconstrained, because it is difficult to find/study them.
So to answer the main part of your question - yes it does appear to be more favourable to form stars as part of binary or multiple systems and this is especially true of the progenitors of neutron stars (and black holes). The reasons for this are as yet unclear, not least because the formation of massive stars is still an unsolved problem.
Note that the fraction of pulsars that are part of binary systems would be expected to be lower than the birth binarity frequency of their progenitors. The supernova explosion that produces the pulsar can disrupt the binary system in many cases, as evidenced by the high velocity dispersion of the known young pulsars ( http://arxiv.org/abs/astro-ph/0402282 ) . In addition, about 20% of high mass stars are seen as "runaways" from star forming regions, probably ejected from multiple systems ( e.g. http://adsabs.harvard.edu/abs/2011Sci...334.1380F ), and will presumably form isolated neutron stars in the future. On the other hand it is also clear that multiple systems containing pulsars or neutron stars frequently survive the supernova explosion, presumably because the mass and momentum loss is highly symmetric or the binary system is very close and strongly bound.