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$\begingroup$They're not just possible. They're unavoidable by gauge invariance in the presence of the kinetic terms $F_{\mu\nu}F^{\mu\nu}$ for the gauge fields.$\endgroup$
$\begingroup$Ahemm... not so fast. the second one is, of course, but a 4-Z tree coupling is not present in the tree gauge lagrangian: basically there is no nonvanishing trace of a product of two commutators only involving $\tau_3$s.$\endgroup$