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Imagine a charged particle inside a Faraday cage (i.e. charge on outside, zero electric field inside, but non-zero electric potential on the inside). Suppose the charge distributed on the outside of this Faraday cage is changing as a function of time. Now you have a potential on the inside of the conductor that is varying with time, but still no field.

The travelling particle will only "feel" the potential once the new information about the potential gets to the particle from the edges of the Faraday cage (I believe the electromagnetic force/interaction travels at the speed of light if I'm not mistaken). Thus, if we imagine this change in the charge distributed on the outside of the Faraday cage to be smooth, the charge will see an electric potential gradient (the potential on one side of the particle will be 'updated' to a certain value while on the other side it will not be 'updated' yet, and so will be at a different value). This potential gradient will then give rise to a force on the particle.

My question is as follows: Is this idea covered by Maxwell's equations? When I imagine this all playing out with an electron travelling straight through a spherical Faraday cage (with a changing charge amount, neglecting the time it takes for the charges to distribute themselves so as to cancel all internal fields), I imagine the electron behaving wildly, moving every which way in accordance to the changing potentials around it. However, I feel like if I this was dealt with strictly classically, the answer would be no - the electron won't feel a thing.

Also, I have thought about not neglecting the finite time it takes for the charges introduced to the outside of the cage to distribute themselves so as to cancel the field, but I don't see how that could rule out the wild behavior of the electron.

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You should understand how potentials work and how they relate to forces. It is not as simple as saying that information travels at the speed of light. As I will show below, potential can change instantaneously everywhere (but that doesn't mean that information is traveling faster than light.

Lets begin with the Maxwell's equations:

$$ \nabla \cdot \mathbf{E} = \frac{\rho(\mathbf{x},t)}{\epsilon_o} \\ \nabla \cdot \mathbf{B} = 0 \\ \nabla \times \mathbf{E} = -\frac{\partial \mathbf{B}}{\partial t} \\ \nabla \times \mathbf{B} = \mu_o \mathbf{J} + \mu_o \epsilon_o \frac{\partial \mathbf{E}}{\partial t}$$

Since $\nabla \cdot \mathbf{B} = 0$ we can write $\mathbf{B} = \nabla \times \mathbf{A}$ where $\mathbf{A}$ is a vector field that we name the vector potential. Using this in the third Maxwell equation we can write:

$$\nabla \times \left(\mathbf{E} +\frac{\partial \mathbf{A}}{\partial t}\right)=0$$

since we can freely exchange the curl and the partial derivative over time as they are independent. Then using the fact that the curl of a gradient is 0 we define the scalar potential V as: $$\mathbf{E} +\frac{\partial \mathbf{A}}{\partial t} = -\nabla V \\ or\\ \mathbf{E} =-\frac{\partial \mathbf{A}}{\partial t} -\nabla V $$

You will notice that so far we have only used the second and third Maxwell's equations. And we have the scalar and vector potential that can give the electric and magnetic field. But the expressions for the potentials that we have obtained need prior knowledge of the fields to be evaluated. To get around this we will now use the remaining first and fourth of the Max's equations. By doing the substitutions for $\mathbf{E}$ and $\mathbf{B}$ in terms of $\mathbf{A}$ and V in these equations we get:

$$-\nabla^2 V -\frac{\partial}{\partial t} (\nabla \cdot \mathbf{A}) = \frac{\rho}{\epsilon_o}\\ and\\ \left(\nabla^2 \mathbf{A} - \mu_o \epsilon_o \frac{\partial^2 \mathbf{A}}{\partial t^2}\right)-\nabla\left(\nabla \cdot \mathbf{A} + \mu_o \epsilon_o \frac{\partial V}{\partial t}\right) = -\mu_o \mathbf{J} $$

So we have these two PDE's that contain all the information of Max's equations. I guess you could say that they are the integral form of Max's equations. You might be getting tired now. But don't worry, we are getting there. To solve these nasty PDE's we need to make some gauge choices.

So, before I can show you how you should think about potential due to changing charge distributions, I must talk about gauges. There is something called the gauge freedom which basically means that these PDE's don't uniquely specify the potentials. In fact you can add the gradient of any scalar valued function to the vector potential and subtract its partial time derivative from the scalar potential without changing the fields. What this entails is that you can choose the value of $\nabla \cdot \mathbf{A}$ to be equal to 0(Coulomb gauge) or $-\mu_o\epsilon_o \frac{\partial V}{\partial t}$ (Lorentz gauge) among other things(other gauges).

So lets work with Coulomb gauge because it will illustrate my point. Setting the $\nabla \cdot \mathbf{A} = 0$ in the first PDE we get:

$$\nabla^2 V = -\frac{\rho(\mathbf{x}', t)}{\epsilon_o}$$

which you can solve using Green's functions to get:

$$V(\mathbf{x},t) = \frac{1}{4 \pi \epsilon_o} \int \frac{\rho(\mathbf{x}', t)}{|\mathbf{x}'-\mathbf{x}|} d^3 \mathbf{x}'$$

So you see that the potential at $\mathbf{x}$ at time $t$ depends on the charge density at $\mathbf{x}'$ at time $t$. So, a change in the charge distribution will update the scalar potential immediately everywhere. Now, you may be worried that this will break causality. But that won't happen because the vector potential is time dependent unlike the scalar one and to calculate the field (which is the only measurable quantity) you need the vector potential. So, even though a changing charge density on the surface may affect a moving charged particle in a Faraday cage(it doesn't block magnetic fields), one cannot really talk about gradients in the scalar potential due to time dependence as you are implying (at least in Coulomb gauge).

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  • $\begingroup$ Ah ok. If we were to measure the phase shift of the wavefunction of a particle undergoing this instantaneous update of potential, wouldn't we be able to break causality (so long as the length that the detected information must travel in order to become "measured" information is shorter than the distance from the edge of the Faraday cage to another set of synchronized detectors)? $\endgroup$ Commented Apr 17, 2015 at 13:34
  • $\begingroup$ Well, I am not sure about this but I think we cannot deal with quantum particles in this way. For that one would have to go to quantum electrodynamics, and I don't even know what are the equations in that formulation. But I do have a vague idea that the fields are themselves quantized and are represented not as functions but operators. So, I don't think such a discussion lies within the scope of my answer. $\endgroup$
    – gautam1168
    Commented Apr 17, 2015 at 15:18
  • $\begingroup$ @gautam1168, did you include retarded time? $\endgroup$
    – R. Romero
    Commented Apr 22, 2019 at 15:14

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