EDIT: title changed to be more descriptive.
I would like to calculate the capacitance of a material (in plate form with thickness d and a known permittivity $\varepsilon_r$ ) between two sphere electrodes of the same radius.
I could calculate the capacitance using the plate model of a capacitor: $$ \frac {\varepsilon_0 \varepsilon_r A}{d}$$ but how do I determine the effective area A between the sphere electrodes?