In the book of Acheson, it is stated that the material derivative $\frac{D\vec u}{Dt}$ can be considered as an acceleration of a "fluid element" - which is something the author never defined, but my understanding is that a "fluid element" is a physical volume that moves with the streamline it started with such that the fluid particles contained in that volume at any given become the corresponding "fluid element".
However, they also mention that (see exercise 1.8) that when the flow is unsteady, the particle trajectories will not be the same as the streamlines. So, does this mean that the concept of acceleration for a fluid element via $\frac{D\vec u}{Dt}$ is only meaningful and defined for a steady-flow?