I don't understand why it is necessary to state the superposition principle. Reading Griffiths' Introduction to electrodynamics, the superposition principle is described as experimental fact that is not implied by Coulomb's law. Well, it is clear to me that non-linear phenomena can exist, but as far as know, Couloumb's law for two point charges is:
\begin{equation} \vec{F}=\frac{1}{4\pi\epsilon_0}\frac{q_1q_2}{\left|\vec{r_1}-\vec{r_2}\right|^3}\left(\vec{r_1}-\vec{r_2}\right) \end{equation}
with obvious notation. Now, defining it as a vector implies that is sums like vectors ans thus linearity, so this should imply the principle of superposition.
Things would be different if we defined only the modulus of Coulomb's force (without saying it is a vector) and in that case, superposition would be implied.
So, at this point my guess is that first we observe that superposition principle is valid and for this reason we use vectors for forces.
What am I missing here?
P.S. I used electrostatics as a mere example here. The doubt is about the relation between vectors and superposition.