I think the lines you have been looking at have a width contributed to by the spectral resolution of the instrument and Zeeman broadening.
You haven't considered the spectral resolution of the spectrograph. The maximum possible for Hinode spectra is about 0.003 nm (Tsuneta et al. 2007) and there is nothing in the source you have used that says what modes of observation were used or how the spectra have been treated during any subsequent analysis.
In addition to this, there are other broadening mechanisms present. The source you quote is all about Zeeman broadening/splitting of the iron lines that are displayed. The series of spectra show the development of this as you move towards the centre of the sunspot. The top spectrum, which I guess you have used to estimate the intrinsic linewidth (looks like a FWHM of about 0.014 nm) is still going to have unresolved Zeeman components at some level, since it is on the edge of a sunspot.
Bulk Doppler motions are unlikely to contribute much. In spatially unresolved spectra these amount to an extra broadening of about 1 km/s, which is only 0.002 nm at this wavelength. It should be less in the spatially resolved Hinode spectra.