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When I spill water on paper and then the paper dries/the water evaporates, the paper is extremely stiff and crinkly (makes noise when moved).

Why is this? I understand that water breaks hydrogen bonds in between cellulose fibers in paper making it easy to rip, but when it dries, why is it stronger?

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Great question. Wetting leads to a collapse of the cellulose fiber network. When dried, the deformed, "squashed" fibers are in greater contact than they were pre-wetting, and hence give rise to a dense, stiff mesh. A more thorough discussion is in this paper:

"Why does paper get stronger as it dries?" Alvaro Tejado and Theo G.M.van de Ven, Materials Today, 13, September 2010, Pages 42-49.

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