From this previous question Charge, velocity-dependent potentials and Lagrangian where the citation is shown at the page 22, §1.5 of the book Classical Mechanics of Goldstein, we read that
"an electric charge $q$ of mass $m$ moving at a velocity $\mathbf{v}$ in a region containing both electric field $\mathbf E(t,x,y,z)$ and magnetic field $\mathbf B(t,x,y,z)$ ($\mathbf B$ and $\mathbf E$ are derivable from a scalar potential $\phi(t, x, y, z) $ and a vector potential $\mathbf A(t,x,y,z)$), nowing that $$\mathbf E=- \nabla \phi - \frac{\partial {\mathbf A}} {\partial t}, \quad \mathbf B= \nabla \times {\mathbf A}. "\tag{1.61}$$
Why must be
$$\color{red}{\large \mathcal U=q \phi - q {\mathbf A} \cdot{\mathbf v} \quad ?}\tag{1.62}$$
Exist a physics proof of this equality?