For a real scalar field $\phi$, a theory as simple as the $\phi^4$ theory, can exhibit the phenomenon of Spontaneous Symmetry Breaking (SSB). For a complex scalar field $\phi$, a theory as simple as the one described by a potential of the form $V(\phi^*\phi)$ is capable of showing SSB. Why is it that a simple quantum field theory containing only a fermion field $\Psi$ incapable of showing this feature of SSB?
Added after @Dwagg's answer I was a bit sloppy in saying that theories with only fermions do not admit SSB. In QCD, there is chiral symmetry breaking which is related to a nonzero VEV of the operator $\bar{q}q$ for a quark field $q$. But the route is not straightforward.
In classical field theories, the standard way to check whether SSB has occurred is the following. One has a Lagrangian with a potential term $V(\phi)$. When minimized, the minimum of $V(\phi)$ occurs at a nonzero value of $\phi$. In QFT, one says that $\phi$ has got a VEV.
I have not seen such a straightforward route to understand QCD chiral symmetry breaking i.e., no such potential in the QCD Lagrangian. So the question is
Is there a similar way of showing that a nonzero VEV of $\bar{q}q$ is possible by minimizing some "effective potential" $V(\bar{q}q)$ of QCD.?
For the Gross-Neveu model in Dwagg's answer there is already a quartic term in the Lagrangian, and minimizing the potential w.r.t $\bar{\psi}_a\psi_a$ can give rise to SSB. Such a term is not there in QCD Lagrangian.