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Consider an ensemble of electrons which all experienced a collision at time $t=0$. Let $n(t)$ denote the number of electrons in this ensemble.

Assume that the number of electrons $\mathrm{d}n$ from this ensemble experiencing collisions in a time $\mathrm{d}t$ is proportional to $n$, i.e. $$\mathrm d n = -an(t) \mathrm d t,$$ for some consant of proportionality $a$.

Edit. Also assume that at $t=0$ an electric field is switched off.

Why is the relative change in drift velocity $\frac{\mathrm d |\langle \mathbf v \rangle|}{|\langle \mathbf v \rangle|}$ equal to the relative change in the number of electrons which have not yet experienced a collision$-\frac{\mathrm d n}{n}$?

Edit. Noting that the thermal drift velocity is always zero, the contribution of an electron, which experience a collision after $t=0$, to the average velocity will vanish as soon as it experiences a collision. Because then it loses the drift velocity that was induced by the electric field.

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If we consider a small change in drift velocity $\Delta |\langle\mathbf v \rangle|$, I come to the following conclusion: $$ \Delta |\langle \mathbf v \rangle| = -\frac{|\langle \mathbf v \rangle|}{n} \Delta n.$$ Namely, a small amount $\Delta n$ of electrons which have experienced a collision do not contribute an amount $\frac{|\langle \mathbf v \rangle|}{n}$ anymore to the total drift velocity $|\langle \mathbf v \rangle|$. Thus this amount is lost and gives the change in drift velocity. Dividing both sides by $|\langle \mathbf v \rangle|$ and taking infinitesimals gives the desired relation.

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