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How can we mathematically prove that a free electron can't absorb a photon totally?

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It relies on conservation of energy and momentum and the equation for energy in special relativity: $E^2 = (pc)^2 + (mc^2)^2$.

Here you go.

Energy of photon: $E_\gamma = \hbar\omega = p_\gamma c$, where $p_\gamma$ is the momentum of the photon. Assume the electron is initially at rest, so it's energy is simply $m_ec^2$.

By conservation of energy, the energy of the electron after it absorbs the photon is $E_\gamma + m_ec^2$, by conservation of momentum, its momentum is $p_\gamma$.

From relativity we have $E^2 = (pc)^2 + (mc^2)^2$. Subbing in all the values we calculated, we have:

\begin{equation} (E_\gamma + m_ec^2)^2=(p_\gamma c)^2+(m_ec^2)^2 \end{equation}

I will let you verify that this equation cannot hold.

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  • $\begingroup$ Something is off here... How can the electron momentum after interaction equal the incident photon's momentum? Wait... Oh, you're using that show it cannot happen... I see... $\endgroup$ Commented Jan 22, 2016 at 19:53

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