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(according to Steven H. Simon's "The Oxford Solid State Basics")

A well-known approach to describe a one-dimensional chain of atoms is to approximate the potential of each of the atoms quadratically:

![potential well][1]potential well

Therefore, $V(x) \simeq V(x_{eq}) + \frac{\kappa}{2}(x-x_{eq})^2$ and hence $F=-\kappa (x-x_{eq})$.

We can use this approximation to describe compressibility whose coefficient is defined as: $$\beta = -\frac{1}{V} \left (\frac{\partial V}{\partial P} \right )_T$$

In 1D this becomes (I'll skip the T subscript): $$\beta = -\frac{1}{L}\frac{\partial L}{\partial F}=\frac{1}{\kappa x_{eq}}$$ I don't understand how this result was obtained. Isn't $\frac{\partial F}{\partial x}$ simply equal to $-\kappa$? What exactly are we differentiating with respect to? Also, am I right in thinking that the $P \rightarrow F$ transition may be justified because pressure "becomes" force in 1D? [1]: https://i.sstatic.net/zx81v.png

(according to Steven H. Simon's "The Oxford Solid State Basics")

A well-known approach to describe a one-dimensional chain of atoms is to approximate the potential of each of the atoms quadratically:

![potential well][1]

Therefore, $V(x) \simeq V(x_{eq}) + \frac{\kappa}{2}(x-x_{eq})^2$ and hence $F=-\kappa (x-x_{eq})$.

We can use this approximation to describe compressibility whose coefficient is defined as: $$\beta = -\frac{1}{V} \left (\frac{\partial V}{\partial P} \right )_T$$

In 1D this becomes (I'll skip the T subscript): $$\beta = -\frac{1}{L}\frac{\partial L}{\partial F}=\frac{1}{\kappa x_{eq}}$$ I don't understand how this result was obtained. Isn't $\frac{\partial F}{\partial x}$ simply equal to $-\kappa$? What exactly are we differentiating with respect to? Also, am I right in thinking that the $P \rightarrow F$ transition may be justified because pressure "becomes" force in 1D? [1]: https://i.sstatic.net/zx81v.png

(according to Steven H. Simon's "The Oxford Solid State Basics")

A well-known approach to describe a one-dimensional chain of atoms is to approximate the potential of each of the atoms quadratically:

potential well

Therefore, $V(x) \simeq V(x_{eq}) + \frac{\kappa}{2}(x-x_{eq})^2$ and hence $F=-\kappa (x-x_{eq})$.

We can use this approximation to describe compressibility whose coefficient is defined as: $$\beta = -\frac{1}{V} \left (\frac{\partial V}{\partial P} \right )_T$$

In 1D this becomes (I'll skip the T subscript): $$\beta = -\frac{1}{L}\frac{\partial L}{\partial F}=\frac{1}{\kappa x_{eq}}$$ I don't understand how this result was obtained. Isn't $\frac{\partial F}{\partial x}$ simply equal to $-\kappa$? What exactly are we differentiating with respect to? Also, am I right in thinking that the $P \rightarrow F$ transition may be justified because pressure "becomes" force in 1D?

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Compressibility of solids (quadratic approximation)

(according to Steven H. Simon's "The Oxford Solid State Basics")

A well-known approach to describe a one-dimensional chain of atoms is to approximate the potential of each of the atoms quadratically:

![potential well][1]

Therefore, $V(x) \simeq V(x_{eq}) + \frac{\kappa}{2}(x-x_{eq})^2$ and hence $F=-\kappa (x-x_{eq})$.

We can use this approximation to describe compressibility whose coefficient is defined as: $$\beta = -\frac{1}{V} \left (\frac{\partial V}{\partial P} \right )_T$$

In 1D this becomes (I'll skip the T subscript): $$\beta = -\frac{1}{L}\frac{\partial L}{\partial F}=\frac{1}{\kappa x_{eq}}$$ I don't understand how this result was obtained. Isn't $\frac{\partial F}{\partial x}$ simply equal to $-\kappa$? What exactly are we differentiating with respect to? Also, am I right in thinking that the $P \rightarrow F$ transition may be justified because pressure "becomes" force in 1D? [1]: https://i.sstatic.net/zx81v.png