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In explicit symmetry breaking, the equations of motion of a physical system are variant under the broken symmetry; by contrast, for spontaneous symmetry breaking (SSB), these equations are invariant, but the entire system is not because its vacuum (background) is non-invariant. Further use for the SSB characteristic nonlinear realizations (Goldstone mode), and the group theoretical patterns involved.
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Chiral anomaly and decay of the pion
Neutral Pion would not decay (in Your discussed case) only if the constituent quarks forming the neutral pion were massless. The professional answer to Your question can be found here:
http://www.scho …