0
$\begingroup$

I'm working on a problem that states:

Volume of $n$ moles of ideal monatomic gas increased from $V_0$ to $2V_0$ at constant $P_0$ in a quasi-static process. Calculate $\Delta W$, $\Delta Q$, $\Delta E$, and $\Delta S$.

In class, we derived $dS$ as such:

Consider the first law

$$ dE= dQ-PdV$$ since $dE=nC_vdT$, where $C_v$ is specific heat at constant volume, $$ nC_vdT=dQ-PdV $$ Since $dS=\frac{dQ}{T}$ $$ dS= \frac{nC_v}{T}dT+\frac{P}{T}dV $$ by the ideal gas law $\frac{P}{T}=\frac{Nk}{V}$, $$ dS=nC_v\frac{dT}{T}+Nk\frac{dV}{V} $$ integrating from initial state $i$ to final state $f$, this yields $$ \Delta S =nC_v\log\frac{T_f}{T_i}+Nk\log\frac{V_f}{V_i} \tag{1} $$

However, since the process here is isobaric, I can't just use eq. 1 above, correct? Do I instead use the fact that $dQ=nC_pdT$ at constant pressure, thus $$ dS=\frac{nC_pdT}{T} $$ integrating to yield $$ \Delta S = nC_p\log\frac{T_f}{T_i} $$ since $T=\frac{PV}{nR}$, $\frac{T_f}{T_i}=\frac{2P_0V_0}{nR}\frac{nR}{P_0V_0}=2$ therefore $$ \Delta S = nC_p\log2 $$ Is this correct?

$\endgroup$

1 Answer 1

0
$\begingroup$

Hint: For an ideal gas,

$$C_{p}-C_{v}=nR$$

Hope this helps.

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.