0
$\begingroup$

Mathematically, it is obvious that the total orbital angular momentum $L^2$ commutes with the spin-orbit Hamiltonian $\propto\boldsymbol{L}\cdot\boldsymbol{S}$. However, is there an intuitive physical reason for this?

For example, the total angular momentum $J^2$ must commute because there is no external torque, and the total spin $S^2$ must commute because the spin of the electron is constant, but I can't think of any similar argument for $L^2$.

$\endgroup$
2
  • $\begingroup$ Just a small note: J = L + S. Thus if J and S do not change, L cannot change either. $\endgroup$ Commented Oct 3, 2020 at 18:33
  • $\begingroup$ I'm not sure if this works though because $J^2\neq L^2+S^2$. $\endgroup$ Commented Oct 3, 2020 at 20:14

2 Answers 2

0
$\begingroup$

If you are considering energy scales where the $L$ and $S$ quantum numbers still make sense and can be used as the unperturbed basis, then there is not enough energy for the electron to change sub-orbital and hence change its angular momentum $\ell$ (in this case equal to the total angular momentum $L$ as you are considering a single-particle system).

$\endgroup$
0
$\begingroup$

Yes. $\vec L\cdot \vec S$ expands as a sum containing $L_x$, $L_y$ and $L_z$, and $L^2$ commutes with all of these individually so commutes with a sum of these, as it would commute with $\hat n\cdot \vec L$.

One can (in a rather hand-waving way) think of the linear combination of $L_k$ in $\vec S\cdot\vec L$ as defining a “direction” along $\vec S$ (just as $\hat n\cdot \vec L$ is in the direction of $\hat n$) and thus just reorienting the quantization axis. Thus if $\vec S$ is “along” $\hat y$ then so is $\vec L$ and one would the redo angular momentum theory using $\hat y$ as the quantization axis.

$\endgroup$
1
  • $\begingroup$ I said in the question I already find it mathematically obvious, but am looking for an intuitive physical explanation. $\endgroup$ Commented Oct 3, 2020 at 17:58

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.