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I am trying to understand some calculations to get the excitation energy $\Delta E_\text{M} = E_\text{M} - E_0$ (M is the number of domain walls) in the 1d Ising model in the absence of a magnetic field:

$$ H = - J\sum_{i=1}^N s_i s_{i+1} $$

As far as I know, you can take two approaches -- open boundary conditions and periodic boundary conditions. Open boundary conditions means that the Hamiltonian becomes

$$ H_\text{OBC} = - J ( s_1 s_2 + s_2 s_3 + \dots + s_{N-1} s_N )$$

while the periodic boundary conditions lead to

$$ H_\text{PBC} = - J ( s_1 s_2 + s_2 s_3 + \dots + s_{N-1} s_N + s_N s_1 ) .$$

This leads to different ground state energies

$$ E_{0, OBC} = - J ( N - 1 )$$

and

$$ E_{0, PBC} = - J N .$$

If I understood everything correctly, every domain will contribute an energy $- (L_i - 1) J$ (where $L_i$ are just the number of spins in the domain $i$) plus an additional $+J$ per domain wall in the OPC leading to

$$ E_{M, OPC} = - J \sum_{i=1}^M (L_i - 1) + J M = - JN + 2JM = E_{0, OPC} + \Delta E_{M, OPC} $$

but in the PBC, I would get an energy $- J L_i$ per domain plus $0$ per domain wall since the energy contribution is $\propto - JN$. This leads to

$$ E_{M, PBC} = - J \sum_{i=1}^M L_i = - JN = E_{0, PBC} $$

I am really confused by this and I feel like I've mixed things up quite a lot. I was expecting both results to match (or at least to match in thermodynamic limit).

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1 Answer 1

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Simplify your life by rewriting your Hamiltonian as $$H_{\rm OBC} = -J (N-1) -J \sum_{i=2}^N (s_{i-1}s_i -1) $$ and $$ H_{\rm PBC} = -J N -J \sum_{i=1}^N (s_{i-1}s_i -1), $$ where in the latter sum I have set $s_0\equiv s_N$. In the ground states, $s_{i-1}s_i = 1$ for all $i$ and you recover your formulas for $E_{0,{\rm OBC}}$ and $E_{0,{\rm PBC}}$.

Now, if you have $M$ domain walls (that is, $M$ pairs of neighbors with disagreeing spins), then the energy clearly increases by $2MJ$, so $E_{\rm M, OBC} = E_{0,{\rm OBC}} + 2MJ$ and $E_{{\rm M, PBC}} = E_{0,{\rm PBC}} + 2MJ$.

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