I have been reading Anderson's paper, "Absence of diffusion in a certain Random Lattice" and found the concept of inhomogeneous broadening. I couldn't really find a satisfactory explanation with a valid theoretical treatment of the same.
So, What is the quantum mechanical concept behind line broadening phenomenon in many-body physics?

  • $\begingroup$ Anderson's paper is not about many-body physics. The paper deals with a single-particle problem. The only interaction appearing in the model is tunneling between impurity sites. $\endgroup$ – flaudemus Feb 19 at 15:56

The term inhomogeneous broadening refers to the broadening of a resonant transition or an energy level. If you consider an ensemble of objects, each having in principle the same transition energy (or energy level) if isolated, but each of them experiences a different local environment, which shifts the individual transition energies (or energy levels) in an uncontrolled random way, then the measured resonance (or energy level) of the ensemble will be broadened. This is the inhomogeneous broadening.

In Anderon's case, each impurity has a random on-site energy $E_j$, which you can already call a model for inhomogeneous broadening. In addition, there are the coupling matrix elements $V_{ij}$ which, according to Anderson's model, may or may not be stochastic variables as well. All this results in an impurity band, i.e., an inhomogeneously broadened density of states.

The absence of inhomogeneous broadening in this model would mean that neither the $E_j$ nor the $V_{ij}$ are random variables.

  • $\begingroup$ Then what is homogenous broadening? $\endgroup$ – EverydayFoolish Feb 20 at 2:47
  • $\begingroup$ @EverydayFoolish: Homogeneous broadening is caused by mechanisms that are exactly the same for all objects of the ensemble. For example, you can think of the lifetime broadening of a transition energy due to coupling of an atom to the light field. $\endgroup$ – flaudemus Feb 20 at 5:41

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