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I've been working with the Optical theorem in the case in which final and initial states are equals and I have the following doubt. Let's write the scattering matrix $S$ as:

$$S = 1 + i·T \tag1$$

where $T$ is the transition matrix. Therefore, the Optical theorem is:

$$2·Im(T) = T^\dagger T \implies 2·Im(T_{ii}) = \sum_a|T_{ai}|^2 \tag2$$

In Eq. (2), we have imposed the particular case commented above with $a$ any state in between. So my doubt arises from here: if, for Eq. (1), $$<i|S|i> = 1 + i<i|T|i> \implies S_{ii} = 1 + iT_{ii},\tag3$$ then for that particular case, when I computed the $T_{ii}$ and took $$|S_{ii}|^2 = probability\ of\ the\ process\ i \rightarrow i,\tag4$$ I will get a probability greater than 1. But that isn't possible.

What am I misunderstanding?

Thanks in advance!

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    $\begingroup$ What happened to the crossterm $-2{\rm Im} T_{ii}$ in eq. (4)? $\endgroup$ – Qmechanic Oct 22 '18 at 20:00
  • $\begingroup$ They aren't needed in Eq. (3) $\endgroup$ – Vicky Oct 22 '18 at 20:38
  • $\begingroup$ If they aren't needed in Eq(3), neither in Eq. (4) $\endgroup$ – Vicky Oct 22 '18 at 21:00
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You might be assuming the matrix element $T_{ii}$ to be real. If so, then

$$ \lvert S_{ii} \rvert^2 = 1 + \lvert T_{ii} \rvert^2 > 1 $$

Without such an assumption, $$ \begin{align*} \lvert S_{ii} \rvert^2 &= 1 + \lvert T_{ii} \rvert^2 - 2\mathrm{Im}(T_{ii})\\ &= 1 + \lvert T_{ii} \rvert^2 - \sum_a \lvert T_{ai} \rvert^2 \\ &= 1 - \sum_{a \neq i} \lvert T_{ai} \rvert^2 \end{align*} $$

which is smaller than $1$.

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