Well, the metric on the target space (not to be confused with the spacetime metric) $g_{ij}$ looks like
$$g_{ij}\sim \delta_{ij}+(C_{ijkl}X^{k}X^{l})+\mathcal{O}(X^{4}).$$
We can invert this, obtaining ("for small $X$")
$$g^{ij}\sim \delta^{ij}-{D^{ij}}_{kl}X^{k}X^{l}+\mathcal{O}(X^{4})$$
where ${D^{ij}}_{kl}$ are "some coefficients" we could figure out if forced to.
Really, to prove operator ordering ambiguity in the Hamiltonian, you just have to show that
$$H\approx g^{ij}P_{i}P_{j} = \delta^{ij}P_{i}P_{j}-{D^{ij}}_{kl}X^{k}X^{l}P_{i}P_{k}+\mathcal{O}(X^{4}P^{2})$$
has ambiguities when quantized.
How? Well, consider the simpler case of a one-dimensional particle. We see that the Poisson brackets satisfy
$$\tag{1}p^{2}x^{2}=(px)^{2}=\{x^{3},p^{3}\}-p^{2}x\{x^{2},p\}-\{x^{3},p\}p^{2}.$$
Woah, how did we get this equality? Well we use the property
$$ \{fg,h\}=f\{g,h\}+g\{f,h\},\quad\mbox{and}\quad\{f,gh\}=g\{f,h\}+h\{f,g\}.$$ Then we consider $\{x^{3},p^{3}\}$ and do some algebra.
But when (1) is quantized, these equalities fails badly. It's unclear (or ambiguous) what's important to quantize, and how to do it.
In other words, if we have quantization as a map
$$Q:\mathrm{classical}\to\mathrm{quantum}$$
satisfying:
- quantization "puts hats" on position and momentum: $Q(x)=\widehat{x}$ and $Q(p)=\widehat{p}$, and are "represented irreducibly" (this is a technical condition, don't worry too much about it!);
- $Q$ is linear, so $Q(c_{1}f+c_{2}g)=c_{1}Q(f)+c_{2}Q(g)$ where $f,g$ are functions of momentum and position;
- Poisson brackets become $\displaystyle Q(\{f,g\})=\frac{1}{\mathrm{i}\hbar}[Q(f),Q(g)]$;
- The number 1 is mapped to the identity operator $Q(1)=\mathrm{id}$.
We have problems trying to evaluate $Q(x^{2}p^{2})$. Do we have
$$Q(x^{2}p^{2})\stackrel{??}{=}Q(x)^{2}Q(p)^{2}\stackrel{??}{=}Q(xp)^{2}?$$
What happens to equation (1)? It's ambiguous :(
For more on operator ordering ambiguities, see S. Twareque Ali, Miroslav Engliš "Quantization Methods: A Guide for Physicists and Analysts" arXiv:math-ph/0405065.
Also this Hamiltonian is related to Laplacian, which I am not able to understand, why ?
When we work with a linear sigma model, we have $g_{ij}=\delta_{ij}$ and we recover the usual Hamiltonian as the Laplacian (up to some constant).
This can be seen from the formula, and noting in this particular case $g^{ij}=\delta^{ij}$ so we find
$$ H = \frac{1}{2}\delta^{ij}P_{i}P_{j} = \frac{1}{2}P^{i}P_{i}$$
Again, up to some constant. (See equation (10.70) of the book you're reading, and you find $P_{i}=\mathrm{i}\partial/\partial X^{i}$)
And again do not confuse the "target space metric" $g_{ij}$ with the "spacetime metric" which I think you denote by $\eta_{ij}$ (later on in the book, I think the authors use $h_{ij}$ for the "spacetime metric").