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I have seen written in many courses of statistical mechanics that, for two functions of the general coordinates and momenta $f(q,p)$ and $g(q,p)$ to satisfy

$$ \{f,g\}=0 \tag{1} $$ in a 2D phase space is equivalent to demanding that $f$ (or equivalently $g$) is a pure function of $g$ (respectively $f$) so that one can write:

$$f=F(g(q,p)).\tag{2}$$

I am having trouble to understand why this should be the case.

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    $\begingroup$ Eq. (2) might not be true if $g$ is a constant function... $\endgroup$
    – Qmechanic
    Commented Sep 19, 2017 at 14:10
  • $\begingroup$ @Qmechanic You are right but, in that case, you can write $g$ as a function of $f$. The point is that not always both options are possible. Your comment suggested to me the answer below... $\endgroup$ Commented Sep 19, 2017 at 15:09

1 Answer 1

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(Nice result. I did not know.)

The correct statement is the following.

Proposition. Suppose that $f=f(q,p)$ and $g=g(q,p)$ are a pair of smooth functions defined on an open set $\Omega \subset \mathbb R^2$ such that $\{f,g\}=0$ thereon. Then, in a neighborhood of any $(p_0,q_0)\in \Omega$ we can write either $f(p,q) = F(g(p,q))$ or $g(p,q) = G(f(p,q))$ for some smooth function $F=F(x)$ or $G=G(x)$ depending on the said neighborhood.

Proof. The thesis is true if either $f$ or $g$ is constant around $(p_0,q_0)$ since $F$ or $G$ can be chosen constant in that case. So suppose the at least one of the functions is not constant, say $g$. If $g$ is not constant, at least one derivative of $\partial_p g|_{(q_0,p_0)}$ and $\partial_q g|_{(q_0,p_0)}$ does not vanish and therefore it does not vanish in a neighborhood of $(q_0,p_0)$ by continuity. Suppose $\partial_q g|_{(q_0,p_0)}\neq 0$ (the remaining cases are similar). Dini's theorem assures that it is possible to write $q= q(g,p)$ in a neighborhood of the said point where $q= q(g,p)$ is smooth and $g$ and $p$ are independent variables. Therefore $\{f,g\}=0$ can be restated as $$\frac{\partial f}{\partial p} = \frac{\partial f}{\partial q} \frac{\frac{\partial g}{\partial p} }{\frac{\partial g}{\partial q}} = -\frac{\partial f}{\partial q} \frac{\partial q}{\partial p}\tag{1}\:$$ (I used $g= g(q(g,p),p)$, so taking the total $p$ derivative of both sides since $p$ and $g$ are independent variables: $0 = \frac{\partial g}{\partial q} \frac{\partial q}{\partial p}+ \frac{\partial g}{\partial p}$ and therefore $-\frac{\partial g}{\partial p}/ \frac{\partial g}{\partial q} = \frac{\partial q}{\partial p}$). Next consider the composite map $$f^*(g,p) := f(q(g,p),p)\tag{2}$$ Let us compute the $p$-derivative taking (1) into account: $$\frac{\partial f^*}{\partial p}= \frac{\partial f}{\partial p} + \frac{\partial f}{\partial q} \frac{\partial q}{\partial p} = -\frac{\partial f}{\partial q} \frac{\partial q}{\partial p} + \frac{\partial f}{\partial q} \frac{\partial q}{\partial p} =0\:.$$ So $f^*$ in (2) does not depend on $p$, as a consequence $$f(q,p) = f^*(g(q,p))\:,$$ as wanted if defining $F:= f^*$. QED

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  • $\begingroup$ Thank you Valter, I think you pretty much nailed this. Your comment on the constancy of either f or g makes a lot of sense too in the context in which the result is applied where f is the Hamiltonian and g the density in the phase space of a system. The result thus proves that the repartition function only depends on the Hamiltonian of the system. That is; the energy. $\endgroup$
    – jrekier
    Commented Sep 20, 2017 at 8:47
  • $\begingroup$ One quick question to be absolutely precise; when you mention "Dini's theorem", I assume you mean his theorem on the implicit function (en.wikipedia.org/wiki/Implicit_function_theorem) $\endgroup$
    – jrekier
    Commented Sep 20, 2017 at 9:54
  • $\begingroup$ Yes in Italy the theorem of implicit function is called "Dini's theorem" since he was one of the mathematicians who discovered it. $\endgroup$ Commented Sep 20, 2017 at 10:44

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