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From Griffiths, Introduction to Quantum Mechanics, 2nd ed:

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I found $\langle r \rangle =\frac{3a}{2}$ and $\langle r^2 \rangle =3a^2$. Now I need to find the expectation value of x. However, I don't understand their hint. I understand that $r$ is the radius and $r^2=x^2+y^2+z^2$ is the definition for a sphere in cartesian coordinates. I didn't know how to use the part "exploit the symmetry of the ground state".

Edit: I should mention that the answer is $\langle x \rangle =0$ and $\langle x^2 \rangle = \frac{1}{3}\langle r^2 \rangle = a^2$ as given by the solution set. However, I have no clue why.

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    $\begingroup$ The 1s state is spherically symmetric and no angular terms appear, so you can drop them $\endgroup$
    – user108787
    Commented Oct 30, 2016 at 4:07
  • $\begingroup$ The atom is radially symmetrical. $\langle x \rangle =0$ because otherwise the atom would be permanently polarised. $\langle r \rangle =\frac{3a}{2}$ because it's radially symmetrical: the expression is true in all directions. $\endgroup$
    – Gert
    Commented Oct 30, 2016 at 4:11
  • $\begingroup$ I had asked the same question some days back! $\endgroup$ Commented Oct 30, 2016 at 4:25
  • $\begingroup$ @CountTo10 question for you: am I correct in interpreting the term ''nth state of the hydrogen atom'' as the nth level wave function (with energy $E_n$)? $\endgroup$ Commented Oct 30, 2016 at 4:25
  • $\begingroup$ Short answer, or rather the only answer is that it is entirely mathematical....in the sense that $x,y,z$ can vary from $-\infty$ to $\infty$ which gives the $\langle x \rangle$ (the AVERAGE) as zero. It is possible for $\langle x \rangle$ to be zero but $\langle f(x) \rangle$ (namely $r$) to be non zero $\endgroup$ Commented Oct 30, 2016 at 4:30

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In spherical coordinates $r$ is the distance from the origin and can only ever be positive.
So the expectation value $\langle r \rangle$ has to be positive.
However in rectangular Cartesian coordinates $x$ can be both positive and negative.
In the case that you are considering with a spherically symmetric wave function you would expect the electron to spend as much time when $x<0$ as when $x>0$ so the expectation value of $x$, $\langle x \rangle =0$.

Since $x^2$ is always positive you would expect its expectation value to be positive.
To find $\langle x^2 \rangle$ you reason that because there is spherical symmetry $\langle x^2 \rangle =\langle y^2 \rangle =\langle z^2 \rangle$ and then use $\langle r^2 \rangle = \langle x^2 \rangle +\langle y^2 \rangle +\langle z^2 \rangle$ to get your answer.

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