0
$\begingroup$

Generally speaking, one can calculate the work, $W$ (energy) required to compress a volume, $V$ of gas by integrating the pressure-volume 'loop' in a phase-space as

$$W=\oint PdV$$ where $P$ is the pressure.

or alternatively if $W$ and $V$ are expressed as functions of time

$$W(t)=\int_0^t P(t)Q(t)dt$$

where $Q$ is the flow rate giving rise to the volume

From the alternate expression I can solve for pressure to get

$$P(t) = \frac{1}{Q(t)} \frac{d}{dt}W(t)$$

This says that pressure is the time rate of change of work (energy) divided by flow rate. But I'm having a hard time trying to visualize/interpret this meaning.

Can someone please help me interpret this expression?

$\endgroup$
2
  • $\begingroup$ You should be careful with the way you defined $W(t)$. Notice that the integral on the right hand side has no residual $t$-dependence because you are integrating over $t$. You should re-write it as a definite integral like $W(t) = \int_{t_0}^t P(t) Q(t)\, dt$, and if you do this, you see that you have to introduce some initial time $t_0$. This makes sense since how much work is done depends on when the guy checks into work. $\endgroup$ Commented Aug 13, 2015 at 0:22
  • $\begingroup$ @joshphysics Thanks - you are right. Work started at 'the beginning of time' up to some arbitrary time. :) $\endgroup$
    – docscience
    Commented Aug 13, 2015 at 0:29

1 Answer 1

1
$\begingroup$

By the way, it's customary to use primes or some other indicator inside the integral to be slightly less confusing. I.e. $$W(t) = \int_{t_0}^{t} P(t')Q(t')dt'$$

Be careful about how you think about Q(t). You've described it as a "flow rate", but really, you are saying $Q(t) = \frac{dV}{dt}$, or the rate of change of the volume with time.

Now, the term $$P(t)=\frac{1}{Q(t)} \frac{dW(t)}{dt} = \frac{dt}{dV} \frac{dW(t)}{dt}=\frac{dW(t)}{dV}$$ This is telling you that pressure is a measure of how much work you do by changing the volume of your system at a given time. Your original expression was just a slightly odd way of expressing the same thing.

Systems at high pressure have a lot of energy to release, so changing your volume results in a lot of work being done, i.e. $dW/dV$ is large. Taking the opposite example, for a system in vacuum (P(t) = 0) changing the volume does not result in any change in energy or any work being done, hence W(t) = 0, again corresponding to what you'd expect physically.

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.