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Can an electron which is a bound in an atom absorb more than one photon at the same time ? In specific during photo-electric emission can an electron take in more than one photon if one photon doesn't give it the energy required to drift away from the atom

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  • $\begingroup$ One should keep in mind that it is the system "electron+nucleus " that absorbs the photon(s). $\endgroup$
    – anna v
    Commented Mar 3, 2015 at 12:03

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Yes, this is actually often used in a spectroscopic technique called REMPI -- see the image on this wikipedia page https://en.wikipedia.org/wiki/Resonance-enhanced_multiphoton_ionization

There are some important physics techniques that rely on interaction with two photons -- two photon spectroscopy (http://cua.mit.edu/8.421_S06/Chapter9.pdf).

Some other techniques, like Raman spectroscopy, involve interaction with two photons (but one absorbed, one emitted).

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